DRDO Syllabus

Syllabus for Chemical Engineering paper DRDO-SET

1. Process Calculations and Thermodynamics: Laws of conservation of mass and energy; use of tie components; recycle, bypass and purge calculations; degree of freedom analysis. First and Second laws of thermodynamics. First law application to close and open systems. Second law and Entropy Thermodynamic properties of pure substances: equation of state and departure function, properties of mixtures: partial molar properties, fugacity, excess properties and activity coefficients; phase equilibria: predicting VLE of systems; chemical reaction equilibria.
   
   
2. Fluid Mechanics and Mechanical Operations: Fluid statics, Newtonian and non-Newtonian fluids, Bernoulli equation, Macroscopic friction factors, energy balance, dimensional analysis, shell balances, flow through pipeline systems, flow meters, pumps and compressors, packed and fluidized beds, elementary boundary layer theory, size reduction and size separation; free and hindered settling; centrifuge and cyclones; thickening and classification, filtration, mixing and agitation; conveying of solids.
   
   
3. Heat Transfer: Conduction, convection and radiation, heat transfer coefficients, steady and unsteady heat conduction, boiling, condensation and evaporation; types of heat exchangers and evaporators and their design.
   
   
4. Mass Transfer: Fick’s laws, molecular diffusion in fluids, mass transfer coefficients, film, penetration and surface renewal theories; momentum, heat and mass transfer analogies; stagewise and continuous contacting and stage efficiencies; HTU & NTU concepts design and operation of equipment for distillation, absorption, leaching, liquid-liquid extraction, drying, humidification, dehumidification and adsorption.
   
   
5. Chemical Reaction Engineering: Theories of reaction rates; kinetics of homogeneous reactions, interpretation of kinetic data, single and multiple reactions in ideal reactors, non-ideal reactors; residence time distribution, single parameter model; non-isothermal reactors; kinetics of heterogeneous catalytic reactions; diffusion effects in catalysis.
   
   
6. Process Calculations and Thermodynamics: Laws of conservation of mass and energy; use of tie components; recycle, bypass and purge calculations; degree of freedom analysis. First and Second laws of thermodynamics. First law application to close and open systems. Second law and Entropy Thermodynamic properties of pure substances: equation of state and departure function, properties of mixtures: partial molar properties, fugacity, excess properties and activity coefficients; phase equilibria: predicting VLE of systems; chemical reaction equilibria.
   
   
7. Fluid Mechanics and Mechanical Operations: Fluid statics, Newtonian and non-Newtonian fluids, Bernoulli equation, Macroscopic friction factors, energy balance, dimensional analysis, shell balances, flow through pipeline systems, flow meters, pumps and compressors, packed and fluidized beds, elementary boundary layer theory, size reduction and size separation; free and hindered settling; centrifuge and cyclones; thickening and classification, filtration, mixing and agitation; conveying of solids.
   
   
8. Heat Transfer: Conduction, convection and radiation, heat transfer coefficients, steady and unsteady heat conduction, boiling, condensation and evaporation; types of heat exchangers and evaporators and their design.
   
   
9. Mass Transfer: Fick’s laws, molecular diffusion in fluids, mass transfer coefficients, film, penetration and surface renewal theories; momentum, heat and mass transfer analogies; stagewise and continuous contacting and stage efficiencies; HTU & NTU concepts design and operation of equipment for distillation, absorption, leaching, liquid-liquid extraction, drying, humidification, dehumidification and adsorption.
   
   
10. Chemical Reaction Engineering: Theories of reaction rates; kinetics of homogeneous reactions, interpretation of kinetic data, single and multiple reactions in ideal reactors, non-ideal reactors; residence time distribution, single parameter model; non-isothermal reactors; kinetics of heterogeneous catalytic reactions; diffusion effects in catalysis.
    
    

Syllabus for Computer Science and Engineering paper DRDO-SET

1. Theory of Computation: Regular languages and finite automata, Context free languages and Push-down automata, Recursively enumerable sets and Turing machines, Undecidability; NP-completeness.
   
   
2. Digital Logic: Logic functions, Minimization, Design and synthesis of combinational and sequential circuits; Number representation and computer arithmetic (fixed and floating point).
   
   
3. Computer Organization and Architecture: Machine instructions and addressing modes, ALU and data-path, CPU control design, Memory interface, I/O interface (Interrupt and DMA mode), Instruction pipelining, Cache and main memory, Secondary storage.
   
   
4. Programming and Data Structures: Programming in C; Functions, Recursion, Parameter passing, Scope, Binding; Abstract data types, Arrays, Stacks, Queues, Linked Lists, Trees, Binary search trees, Binary heaps.
   
   
5. Algorithms: Analysis, Asymptotic notation, Notions of space and time complexity, Worst and average case analysis; Design: Greedy approach, Dynamic programming, Divide-and-conquer; Tree and graph traversals, Connected components, Spanning trees, Shortest paths; Hashing, Sorting, Searching.
   
   
6. Compiler Design: Lexical analysis, Parsing, Syntax directed translation, Runtime environments, Intermediate and target code generation, Basics of code optimization.
   
   
7. Operating System: Processes, Threads, Inter-process communication, Concurrency, Synchronization, Deadlock, CPU scheduling, Memory management and virtual memory, File systems, I/O systems, Protection and security.
   
   

Syllabus for Electronics and Communication Engineering paper DRDO-SET

1. Networks: Network graphs: matrices associated with graphs; incidence, fundamental cut set and fundamental circuit matrices. Solution methods: nodal and mesh analysis. Network theorems: superposition, Thevenin and Norton’s maximum power transfer, Wye-Delta transformation. Steady state sinusoidal analysis using phasors. Linear constant coefficient differential equations; time domain analysis of simple RLC circuits, Solution of network equations using Laplace transform: frequency domain analysis of RLC circuits. 2-port network parameters: driving point and transfer functions. State equations for networks.
   
   
2. Electronic Devices: Energy bands in silicon, intrinsic and extrinsic silicon. Carrier transport in silicon: diffusion current, drift current, mobility, and resistivity. Generation and recombination of carriers. p-n junction diode, Zener diode, tunnel diode, BJT, JFET, MOS capacitor, MOSFET, LED, p-I-n and avalanche photo diode, Basics of LASERs. Device technology: integrated circuits fabrication process, oxidation, diffusion, ion implantation, photolithography, n-tub, p-tub and twin-tub CMOS process.
   
   
3. Analog Circuits: Small Signal Equivalent circuits of diodes, BJTs, MOSFETs and analog CMOS. Simple diode circuits, clipping, clamping, rectifier. Biasing and bias stability of transistor and FET amplifiers. Amplifiers: single-and multi-stage, differential and operational, feedback, and power. Frequency response of amplifiers. Simple op-amp circuits. Filters. Sinusoidal oscillators; criterion for oscillation; single-transistor and op-amp configurations. Function generators and wave-shaping circuits, 555 Timers. Power supplies.
   
   
4. Digital Circuits: Boolean algebra, minimization of Boolean functions; logic gates; digital IC families (DTL, TTL, ECL, MOS, CMOS). Combinatorial circuits: arithmetic circuits, code converters, multiplexers, decoders, PROMs and PLAs. Sequential circuits: latches and flip-flops, counters and shift-registers. Sample and hold circuits, ADCs, DACs. Semiconductor memories. Microprocessor(8085): architecture, programming, memory and I/O interfacing.
   
   Fourier series, continuous-time and discrete-time Fourier Transform, DFT and FFT, z-transform. Sampling theorem. Linear Time-Invariant (LTI) Systems: definitions and properties; causality, stability, impulse response, convolution, poles and zeros, parallel and cascade structure, frequency response, group delay, phase delay. Signal transmission through LTI systems.
   
   
5. Control Systems: Basic control system components; block diagrammatic description, reduction of block diagrams. Open loop and closed loop (feedback) systems and stability analysis of these systems. Signal flow graphs and their use in determining transfer functions of systems; transient and steady state analysis of LTI control systems and frequency response. Tools and techniques for LTI control system analysis: root loci, Routh-Hurwitz criterion, Bode and Nyquist plots. Control system compensators: elements of lead and lag compensation, elements of Proportional-Integral-Derivative (PID) control. State variable representation and solution of state equation of LTI control systems.
   
   
6. Communications: Random signals and noise: probability, random variables, probability density function, autocorrelation, power spectral density. Analog communication systems: amplitude and angle modulation and demodulation systems, spectral analysis of these operations, superheterodyne receivers; elements of hardware, realizations of analog communication systems; signal-to-noise ratio (SNR) calculations for amplitude modulation (AM) and frequency modulation (FM) for low noise conditions. Fundamentals of information theory and channel capacity theorem. Digital communication systems: pulse code modulation (PCM), differential pulse code modulation (DPCM), digital modulation schemes: amplitude, phase and frequency shift keying schemes (ASK, PSK, FSK), matched filter receivers, bandwidth consideration and probability of error calculations for these schemes. Basics of TDMA, FDMA and CDMA and GSM.
   
   
7. Electromagnetics: Elements of vector calculus: divergence and curl; Gauss’ and Stokes’ theorems, Maxwell’s equations: differential and integral forms. Wave equation, Poynting vector. Plane waves: propagation through various media; reflection and refraction; phase and group velocity; skin depth. Transmission lines: characteristic impedance; impedance transformation; Smith chart; impedance matching; S parameters, pulse excitation. Waveguides: modes in rectangular waveguides; boundary conditions; cut-off frequencies; dispersion relations. Basics of propagation in dielectric waveguide and optical fibers. Basics of Antennas: Dipole antennas; radiation pattern; antenna gain.
   
   

Syllabus for Electrical Engineering paper DRDO-SET

1. Electric Circuits and Fields: Network graph, KCL, KVL, node and mesh analysis, transient response of dc and ac networks; sinusoidal steady-state analysis, resonance, basic filter concepts; ideal current and voltage sources, Thevenin’s, Norton’s and Superposition and Maximum Power Transfer theorems, two-port networks, three phase circuits; Gauss Theorem, electric field and potential due to point, line, plane and spherical charge distributions; Ampere’s and Biot-Savart’s laws; inductance; dielectrics; capacitance.
   
   
2. Signals and Systems: Representation of continuous and discrete-time signals; shifting and scaling operations; linear, time-invariant and causal systems; Fourier series representation of continuous periodic signals; sampling theorem; Fourier, Laplace and Z transforms.
   
   
3. Electrical Machines: Single phase transformer - equivalent circuit, phasor diagram, tests, regulation and efficiency; three phase transformers - connections, parallel operation; auto-transformer; energy conversion principles; DC machines - types, windings, generator characteristics, armature reaction and commutation, starting and speed control of motors; three phase induction motors - principles, types, performance characteristics, starting and speed control; single phase induction motors; synchronous machines - performance, regulation and parallel operation of generators, motor starting, characteristics and applications; servo and stepper motors.
   
   
4. Power Systems: Basic power generation concepts; transmission line models and performance; cable performance, insulation; corona and radio interference; distribution systems; per-unit quantities; bus impedance and admittance matrices; load flow; voltage control; power factor correction; economic operation; symmetrical components; fault analysis; principles of over-current, differential and distance protection; solid state relays and digital protection; circuit breakers; system stability concepts, swing curves and equal area criterion; HVDC transmission and FACTS concepts.
   
   
5. Control Systems: Principles of feedback; transfer function; block diagrams; steady-state errors; Routh and Niquist techniques; Bode plots; root loci; lag, lead and lead-lag compensation; state space model; state transition matrix, controllability and observability.
   
   
6. Electrical and Electronic Measurements: Bridges and potentiometers; PMMC, moving iron, dynamometer and induction type instruments; measurement of voltage, current, power, energy and power factor; instrument transformers; digital voltmeters and multimeters; phase, time and frequency measurement; Q-meters; oscilloscopes; potentiometric recorders; error analysis.
   
   
7. Analog and Digital Electronics: Characteristics of diodes, BJT, FET; amplifiers - biasing, equivalent circuit and frequency response; oscillators and feedback amplifiers; operational amplifiers - characteristics and applications; simple active filters; VCOs and timers; combinational and sequential logic circuits; multiplexer; Schmitt trigger; multi-vibrators; sample and hold circuits; A/D and D/A converters; 8-bit microprocessor basics, architecture, programming and interfacing.
   
   
8. Power Electronics and Drives: Semiconductor power diodes, transistors, thyristors, triacs, GTOs, MOSFETs and IGBTs - static characteristics and principles of operation; triggering circuits; phase control rectifiers; bridge converters - fully controlled and half controlled; principles of choppers and inverters; basis concepts of adjustable speed dc and ac drives
   
   

Syllabus for Instrumentation Engineering paper DRDO-SET

1. Basics of Circuits and Measurement Systems: Kirchoff’s laws, mesh and nodal Analysis. Circuit theorems. One-port and two-port Network Functions. Static and dynamic characteristics of Measurement Systems. Error and uncertainty analysis. Statistical analysis of data and curve fitting.
   
   
2. Transducers, Mechanical Measurement and Industrial Instrumentation: Resistive, Capacitive, Inductive and piezoelectric transducers and their signal conditioning. Measurement of displacement, velocity and acceleration (translational and rotational), force, torque, vibration and shock. Measurement of pressure, flow, temperature and liquid level. Measurement of pH, conductivity, viscosity and humidity.
   
   
3. Analog Electronics :Characteristics of diode, BJT, JFET and MOSFET. Diode circuits. Transistors at low and high frequencies, Amplifiers, single and multi-stage. Feedback amplifiers. Operational amplifiers, characteristics and circuit configurations. Instrumentation amplifier. Precision rectifier. V-to-I and I-to-V converter. Op-Amp based active filters. Oscillators and signal generators.
   
   
4. Digital Electronics: Combinational logic circuits, minimization of Boolean functions. IC families, TTL, MOS and CMOS. Arithmetic circuits. Comparators, Schmitt trigger, timers and mono-stable multi-vibrator. Sequential circuits, flip-flops, counters, shift registers. Multiplexer, S/H circuit. Analog-to-Digital and Digital-to-Analog converters. Basics of number system. Microprocessor applications, memory and input-output interfacing. Microcontrollers.
   
   
5. Signals, Systems and Communications: Periodic and aperiodic signals. Impulse response, transfer function and frequency response of first- and second order systems. Convolution, correlation and characteristics of linear time invariant systems. Discrete time system, impulse and frequency response. Pulse transfer function. IIR and FIR filters. Amplitude and frequency modulation and demodulation. Sampling theorem, pulse code modulation. Frequency and time division multiplexing. Amplitude shift keying, frequency shift keying and pulse shift keying for digital modulation.
   
   
6. Electrical and Electronic Measurements: Bridges and potentiometers, measurement of R,L and C. Measurements of voltage, current, power, power factor and energy. A.C & D.C current probes. Extension of instrument ranges. Q-meter and waveform analyzer. Digital voltmeter and multi-meter. Time, phase and frequency measurements. Cathode ray oscilloscope. Serial and parallel communication. Shielding and grounding.
   
   
7. Control Systems and Process Control: Feedback principles. Signal flow graphs. Transient Response, steady-state-errors. Routh and Nyquist criteria. Bode plot, root loci. Time delay systems. Phase and gain margin. State space representation of systems. Mechanical, hydraulic and pneumatic system components. Synchro pair, servo and step motors. On-off, cascade, P, P-I, P-I-D, feed forward and derivative controller, Fuzzy controllers.
   
   
8. Analytical, Optical and Biomedical Instrumentation: Mass spectrometry. UV, visible and IR spectrometry. X-ray and nuclear radiation measurements. Optical sources and detectors, LED, laser, Photo-diode, photo-resistor and their characteristics. Interferometers, applications in metrology. Basics of fiber optics. Biomedical instruments, EEG, ECG and EMG. Clinical measurements. Ultrasonic transducers and Ultrasonography. Principles of Computer Assisted Tomography.
   
   

Syllabus for Mechanical Engineering paper DRDO-SET

1. Engineering Mechanics: Free body diagrams and equilibrium; trusses and frames; virtual work; kinematics and dynamics of particles and of rigid bodies in plane motion, including impulse and momentum (linear and angular) and energy formulations; impact.
   
   
2. Strength of Materials: Stress and strain, stress-strain relationship and elastic constants, Mohr’s circle for plane stress and plane strain, thin cylinders; shear force and bending moment diagrams; bending and shear stresses; deflection of beams; torsion of circular shafts; Euler’s theory of columns; strain energy methods; thermal stresses.
   
   
3. Theory of Machines: Displacement, velocity and acceleration analysis of plane mechanisms; dynamic analysis of slider-crank mechanism; gear trains; flywheels.
4. Vibrations: Free and forced vibration of single degree of freedom systems; effect of damping; vibration isolation; resonance, critical speeds of shafts.
   
   
5. Design: Design for static and dynamic loading; failure theories; fatigue strength and the S-N diagram; principles of the design of machine elements such as bolted, riveted and welded joints, shafts, spur gears, rolling and sliding contact bearings, brakes and clutches.
   
   
6. Fluid Mechanics: Fluid properties; fluid statics, manometry, buoyancy; control-volume analysis of mass, momentum and energy; fluid acceleration; differential equations of continuity and momentum; Bernoulli’s equation; viscous flow of incompressible fluids; boundary layer; elementary turbulent flow; flow through pipes, head losses in pipes, bends etc.
   
   
7. Heat-Transfer: Modes of heat transfer; one dimensional heat conduction, resistance concept, electrical analogy, unsteady heat conduction, fins; dimensionless parameters in free and forced convective heat transfer, various correlations for heat transfer in flow over flat plates and through pipes; thermal boundary layer; effect of turbulence; radiative heat transfer, black and grey surfaces, shape factors, network analysis; heat exchanger performance, LMTD and NTU methods.
   
   
8. Thermodynamics: Zeroth, First and Second laws of thermodynamics; thermodynamic system and processes; Carnot cycle. irreversibility and availability; behaviour of ideal and real gases, properties of pure substances, calculation of work and heat in ideal processes; analysis of thermodynamic cycles related to energy conversion.
   
   
9. Applications: Power Engineering: Steam Tables, Rankine, Brayton cycles with regeneration and reheat. I.C. Engines: air-standard Otto, Diesel cycles. Refrigeration and air-conditioning: Vapour refrigeration cycle, heat pumps, gas refrigeration, Reverse Brayton cycle; moist air: psychrometric chart, basic psychrometric processes. Turbomachinery: Pelton-wheel, Francis and Kaplan turbines — impulse and reaction principles, velocity diagrams.
   
   
10. Engineering Materials: Structure and properties of engineering materials, heat treatment, stress-strain diagrams for engineering materials.
    
    
11. Metal Casting: Design of patterns, moulds and cores; solidification and cooling; riser and gating design, design considerations.
    
    
12. Forming: Plastic deformation and yield criteria; fundamentals of hot and cold working processes; load estimation for bulk (forging, rolling, extrusion, drawing) and sheet (shearing, deep drawing, bending) metal forming processes; principles of powder metallurgy.
    
    
13. Joining: Physics of welding, brazing and soldering; adhesive bonding; design considerations in welding.
    
    
14. Machining and Machine Tool Operations: Mechanics of machining, single and multi-point cutting tools, tool geometry and materials, tool life and wear; economics of machining; principles of non-traditional machining processes; principles of work holding, principles of design of jigs and fixtures
    
    
15. Metrology and Inspection: Limits, fits and tolerances; linear and angular measurements; comparators; gauge design; interferometry; form and finish measurement; alignment and testing methods; tolerance analysis in manufacturing and assembly.
    
    
16. Computer Integrated Manufacturing: Basic concepts of CAD/CAM and their integration tools.
    
    
17. Production Planning and Control: Forecasting models, aggregate production planning, scheduling, materials requirement planning.
    
    
18. Inventory Control: Deterministic and probabilistic models; safety stock inventory control systems.
    
    
19. Operations Research: Linear programming, simplex and duplex method, transportation, assignment, network flow models, simple queuing models, PERT and CPM.
    
    

Syllabus for Metallurgical Engineering paper DRDO-SET

1. Thermodynamics and Rate Processes: Laws of thermodynamics, activity, equilibrium constant, applications to metallurgical systems, solutions, phase equilibria, Ellingham and phase stability diagrams, thermodynamics of surfaces, interfaces and defects, adsorption and segregation; basic kinetic laws, order of reactions, rate constants and rate limiting steps; principles of electro chemistry- single electrode potential, electro-chemical cells and polarizations, aqueous corrosion and protection of metals, oxidation and high temperature corrosion – characterization and control; heat transfer – conduction, convection and heat transfer coefficient relations, radiation, mass transfer – diffusion and Fick’s laws, mass transfer coefficients; momentum transfer – concepts of viscosity, shell balances, Bernoulli’s equation, friction factors.
   
   
2. Extractive Metallurgy: Minerals of economic importance, comminution techniques, size classification, Flotation, gravity and other methods of mineral processing; agglomeration, pyro- hydro- and electro-metallurgical processes; material and energy balances; principles and processes for the extraction of non-ferrous metals – aluminium, copper, zinc, lead, magnesium, nickel, titanium and other rare metals; iron and steel making – principles, role structure and properties of slags, metallurgical coke, blast furnace, direct reduction processes, primary and secondary steel making, ladle metallurgy operations including deoxidation, desulphurization, sulphide shape control, inert gas rinsing and vacuum reactors; secondary refining processes including AOD, VAD, VOD, VAR and ESR; ingot and continuous casting; stainless steel making, furnaces and refractories.
   
   
3. Physical Metallurgy: Crystal structure and bonding characteristics of metals, alloys, ceramics and polymers, structure of surfaces and interfaces, nano-crystalline and amorphous structures; solid solutions; solidification; phase transformation and binary phase diagrams; principles of heat treatment of steels, cast iron and aluminum alloys; surface treatments; recovery, recrystallization and grain growth; industrially important ferrous and non-ferrous alloys; elements of X-ray and electron diffraction; principles of scanning and transmission electron microscopy; industrial ceramics, polymers and composites; electronic basis of thermal, optical, electrical and magnetic properties of materials; electronic and opto-electronic materials.
   
   
4. Mechanical Metallurgy: Elasticity, yield criteria and plasticity; defects in crystals; elements of dislocation theory – types of dislocations, slip and twinning, source and multiplication of dislocations, stress fields around dislocations, partial dislocations, dislocation interactions and reactions; strengthening mechanisms; tensile, fatigue and creep behaviour; super-plasticity; fracture – Griffith theory, basic concepts of linear elastic and elasto-plastic fracture mechanics, ductile to brittle transition, fracture toughness; failure analysis; mechanical testing – tension, compression, torsion, hardness, impact, creep, fatigue, fracture toughness and formability.
   
   
5. Manufacturing Processes: Metal casting – patterns and moulds including mould design involving feeding, gating and risering, melting, casting practices in sand casting, permanent mould casting, investment casting and shell moulding, casting defects and repair; hot, warm and cold working of metals, Metal forming - fundamentals of metal forming processes of rolling, forging, extrusion, wire drawing and sheet metal forming, defects in forming; Metal joining - soldering, brazing and welding, common welding processes of shielded metal arc welding, gas metal arc welding, gas tungsten arc welding and submerged arc welding; welding metallurgy, problems associated with welding of steels and aluminium alloys, defects in welded joints; powder metallurgy; NDT using dye-penetrant, ultrasonic, radiography, eddy current, acoustic emission and magnetic particle methods.
   
   

Syllabus for Chemistry paper DRDO-SET

1. Structure: Quantum theory: principles and techniques; applications to a particle in a box, harmonic oscillator, rigid rotor and hydrogen atom; valence bond and molecular orbital theories, Hückel approximation; approximate techniques: variation and perturbation; symmetry, point groups; rotational, vibrational, electronic, NMR, and ESR spectroscopy
   
   
2. Equilibrium: Kinetic theory of gases; First law of thermodynamics, heat, energy, and work; second law of thermodynamics and entropy; third law and absolute entropy; free energy; partial molar quantities; ideal and non-ideal solutions; phase transformation: phase rule and phase diagrams - one, two, and three component systems; activity, activity coefficient, fugacity, and fugacity coefficient; chemical equilibrium, response of chemical equilibrium to temperature and pressure; colligative properties; Debye-Hückel theory; thermodynamics of electrochemical cells; standard electrode potentials: applications - corrosion and energy conversion; molecular partition function (translational, rotational, vibrational, and electronic).
   
   
3. Kinetics: Rates of chemical reactions, temperature dependence of chemical reactions; elementary, consecutive, and parallel reactions; steady state approximation; theories of reaction rates - collision and transition state theory, relaxation kinetics, kinetics of photochemical reactions and free radical polymerization, homogeneous catalysis, adsorption isotherms and heterogeneous catalysis.
   
   
4. Main group elements: General characteristics, allotropes, structure and reactions of simple and industrially important compounds: boranes, carboranes, silicones, silicates, boron nitride, borazines and phosphazenes. Hydrides, oxides and oxoacids of pnictogens (N, P), chalcogens (S, Se & Te) and halogens, xenon compounds, pseudo halogens and interhalogen compounds. Shapes of molecules and hard- soft acid base concept. Structure and Bonding (VBT) of B, Al, Si, N, P, S, Cl compounds. Allotropes of carbon: graphite, diamond, C60. Synthesis and reactivity of inorganic polymers of Si and P.
   
   
5. Transition Elements: General characteristics of d and f block elements; coordination chemistry: structure and isomerism, stability, theories of metal- ligand bonding (CFT and LFT), mechanisms of substitution and electron transfer reactions of coordination complexes. Electronic spectra and magnetic properties of transition metal complexes, lanthanides and actinides. Metal carbonyls, metal- metal bonds and metal atom clusters, metallocenes; transition metal complexes with bonds to hydrogen, alkyls, alkenes and arenes; metal carbenes; use of organometallic compounds as catalysts in organic synthesis. Bioinorganic chemistry of Na, K. Mg, Ca, Fe, Co, Zn, Cu and Mo. Solids: Crystal systems and lattices, miller planes, crystal packing, crystal defects; Bragg’s Law, ionic crystals, band theory, metals and semiconductors, Different structures of AX, AX2, ABX3 compounds, spinels.
   
   
6. Instrumental methods of analysis: Atomic absorption and emission spectroscopy including ICP-AES, UV- visible spectrophotometry, NMR, mass, Mossbauer spectroscopy (Fe and Sn), ESR spectroscopy, chromatography including GC and HPLC and electro-analytical methods (Coulometry, cyclic voltammetry, polarography – amperometry, and ion selective electrodes).
   
   
7. Stereochemistry: Chirality of organic molecules with or without chiral centres. Specification of configuration in compounds having one or more stereogenic centres. Enantiotopic and diastereotopic atoms, groups and faces. Stereoselective and stereospecific synthesis. Conformational analysis of acyclic and cyclic compounds. Geometrical isomerism. Configurational and conformational effects on reactivity and selectivity/specificity.
   
   
8. Reaction mechanism: Methods of determining reaction mechanisms. Nucleophilic and electrophilic substitutions and additions to multiple bonds. Elimination reactions. Reactive intermediates- carbocations, carbanions, carbenes, nitrenes, arynes, free radicals. Molecular rearrangements involving electron deficient atoms.
   
   
9. Organic synthesis: Synthesis, reactions, mechanisms and selectivity involving the following- alkenes, alkynes, arenes, alcohols, phenols, aldehydes, ketones, carboxylic acids and their derivatives, halides, nitro compounds and amines. Use of compounds of Mg, Li, Cu, B and Si in organic synthesis. Concepts in multistep synthesis-retrosynthetic analysis, disconnections, synthons, synthetic equivalents, reactivity umpolung, selectivity, protection and deprotection of functional groups.
   
   
10. Pericyclic reactions: Electrocyclic, cycloaddition and sigmatropic reactions. Orbital correlation, FMO and PMO treatments.
    
    
11. Photochemistry: Basic principles. Photochemistry of alkenes, carbonyl compounds, and arenes. Photooxidation and photoreduction. Di-p- methane rearrangement, Barton reaction.
    
    
12. Heterocyclic compounds: Structure, preparation, properties and reactions of furan, pyrrole, thiophene, pyridine, indole and their derivatives.
    
    
13. Biomolecules: Structure, properties and reactions of mono- and di-saccharides, physicochemical properties of amino acids, chemical synthesis of peptides, structural features of proteins, nucleic acids, steroids, terpenoids, carotenoids, and alkaloids.
    
    
14. Spectroscopy: Principles and applications of UV-visible, IR, NMR and Mass spectrometry in the determination of structures of organic molecules.
    
    

Syllabus for Chemistry paper DRDO-SET

1. Mathematical Physics: Linear vector space; matrices; vector calculus; linear differential equations; elements of complex analysis; Laplace transforms, Fourier analysis, elementary ideas about tensors.
   
   
2. Classical Mechanics: Conservation laws; central forces, Kepler problem and planetary motion; collisions and scattering in laboratory and centre of mass frames; mechanics of system of particles; rigid body dynamics; moment of inertia tensor; noninertial frames and pseudo forces; variational principle; Lagrange’s and Hamilton’s formalisms; equation of motion, cyclic coordinates, Poisson bracket; periodic motion, small oscillations, normal modes; special theory of relativity – Lorentz transformations, relativistic kinematics, mass-energy equivalence.
   
   
3. Electromagnetic Theory: Solution of electrostatic and magnetostatic problems including boundary value problems; dielectrics and conductors; Biot-Savart’s and Ampere’s laws; Faraday’s law; Maxwell’s equations; scalar and vector potentials; Coulomb and Lorentz gauges; Electromagnetic waves and their reflection, refraction, interference, diffraction and polarization. Poynting vector, Poynting theorem, energy and momentum of electromagnetic waves; radiation from a moving charge.
   
   
4. Quantum Mechanics: Physical basis of quantum mechanics; uncertainty principle; Schrodinger equation; one, two and three dimensional potential problems; particle in a box, harmonic oscillator, hydrogen atom; linear vectors and operators in Hilbert space; angular momentum and spin; addition of angular momenta; time independent perturbation theory; elementary scattering theory.
   
   
5. Thermodynamics and Statistical Physics: Laws of thermodynamics; macrostates and microstates; phase space; probability ensembles; partition function, free energy, calculation of thermodynamic quantities; classical and quantum statistics; degenerate Fermi gas; black body radiation and Planck’s distribution law; Bose-Einstein condensation; first and second order phase transitions, critical point.
   
   
6. Atomic and Molecular Physics: Spectra of one- and many-electron atoms; LS and jj coupling; hyperfine structure; Zeeman and Stark effects; electric dipole transitions and selection rules; X-ray spectra; rotational and vibrational spectra of diatomic molecules; electronic transition in diatomic molecules, Franck-Condon principle; Raman effect; NMR and ESR; lasers.
   
   
7. Solid State Physics: Elements of crystallography; diffraction methods for structure determination; bonding in solids; elastic properties of solids; defects in crystals; lattice vibrations and thermal properties of solids; free electron theory; band theory of solids; metals, semiconductors and insulators; transport properties; optical, dielectric and magnetic properties of solids; elements of superconductivity.
   
   
8. Nuclear and Particle Physics: Nuclear radii and charge distributions, nuclear binding energy, Electric and magnetic moments; nuclear models, liquid drop model - semi-empirical mass formula, Fermi gas model of nucleus, nuclear shell model; nuclear force and two nucleon problem; Alpha decay, Beta-decay, electromagnetic transitions in nuclei; Rutherford scattering, nuclear reactions, conservation laws; fission and fusion; particle accelerators and detectors; elementary particles, photons, baryons, mesons and leptons; quark model.
   
   
9. Electronics: Network analysis; semiconductor devices; Bipolar Junction Transistors, Field Effect Transistors, amplifier and oscillator circuits; operational amplifier, negative feedback circuits , active filters and oscillators; rectifier circuits, regulated power supplies; basic digital logic circuits, sequential circuits, flip-flops, counters, registers, A/D and D/A conversion.